An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emissionElectronic supplementary information (ESI) available: Experimental procedure, additional figures, table for crystallographic data, PXRD, TGA, FT-IR, luminescence spectrum of the ligand and the CIE coordinates of emissions excited at different wavelengths. CCDC 912851. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc38655d
The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd 7 Rb} n helix and nanoscale {Cd 16 Rb 4 } and {Cd 18 Rb 2 } rings, has been constructed and structurally characterized. This compound exhibits white-light emissi...
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Main Authors | , , , , , |
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Format | Journal Article |
Language | English |
Published |
19.02.2013
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Online Access | Get full text |
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Summary: | The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd
7
Rb}
n
helix and nanoscale {Cd
16
Rb
4
} and {Cd
18
Rb
2
} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.
An unprecedented 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a {Cd
7
Rb}
n
helix and 20-membered {Cd
16
Rb
4
} and {Cd
18
Rb
2
} rings, was constructed and characterized. It exhibits white-light emission and a wavelength-dependent photochromic response. |
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Bibliography: | Electronic supplementary information (ESI) available: Experimental procedure, additional figures, table for crystallographic data, PXRD, TGA, FT-IR, luminescence spectrum of the ligand and the CIE coordinates of emissions excited at different wavelengths. CCDC For ESI and crystallographic data in CIF or other electronic format see DOI 912851 10.1039/c3cc38655d |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c3cc38655d |