A 3-D chiral organic-inorganic hybrid zinc vanadate assembled from helical unitsElectronic supplementary information (ESI) available: Crystal data in CIF format, XRD, UV-vis absorption spectra and DFT calculations. CCDC 906120. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt32670a
A novel 3-D chiral organic-inorganic hybrid zinc vanadate, [Zn 2 (μ-en)V 2 O 7 ] n (1, en = ethylenediamine), which is assembled from rare 1-D [(ZnO 3 )(μ-en)(ZnO 4 )] n helical chains and dimeric [V 2 O 7 ] units, has been hydrothermally synthesized. The theoretical band structure and optical prope...
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| Main Authors | , , , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
27.03.2013
|
| Online Access | Get full text |
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| Summary: | A novel 3-D chiral organic-inorganic hybrid zinc vanadate, [Zn
2
(μ-en)V
2
O
7
]
n
(1, en = ethylenediamine), which is assembled from rare 1-D [(ZnO
3
)(μ-en)(ZnO
4
)]
n
helical chains and dimeric [V
2
O
7
] units, has been hydrothermally synthesized. The theoretical band structure and optical properties have also been studied.
A unique 3-D chiral organic-inorganic hybrid zinc vanadate, [Zn
2
(μ-en)V
2
O
7
]
n
(
1
, en = ethylenediamine), which is assembled from rare 1-D [(ZnO
3
)(μ-en)(ZnO
4
)]
n
helical chains and dimeric [V
2
O
7
] units, has been hydrothermally synthesized under spontaneous resolution without any chiral auxiliary. |
|---|---|
| Bibliography: | 906120 For ESI and crystallographic data in CIF or other electronic format see DOI 10.1039/c2dt32670a Electronic supplementary information (ESI) available: Crystal data in CIF format, XRD, UV-vis absorption spectra and DFT calculations. CCDC |
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c2dt32670a |