Targeted synthesis of a mesoporous triptycene-derived covalent organic frameworkElectronic supplementary information (ESI) available: Experimental procedures, characterization methods, and gas sorption studies. See DOI: 10.1039/c2ce26487k
The synthesis and characterization of a highly porous triptycene-derived covalent organic framework (TDCOF-5) and its performance in small gas storage are reported. TDCOF-5 crystallizes into a 2D mesoporous network that contains accessible boron sites, exhibits high surface area (SA Lang = 3832 m 2...
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Main Authors | , , , , |
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Format | Journal Article |
Language | English |
Published |
28.01.2013
|
Online Access | Get full text |
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Summary: | The synthesis and characterization of a highly porous triptycene-derived covalent organic framework (TDCOF-5) and its performance in small gas storage are reported. TDCOF-5 crystallizes into a 2D mesoporous network that contains accessible boron sites, exhibits high surface area (SA
Lang
= 3832 m
2
g
−1
), and high gas uptake under low pressure settings.
A mesoporous triptycene-derived 2D COF has been prepared and fully characterized. The use of triptycene leads to a high surface area (SA
Lang
= 3832 m
2
g
−1
), accessible boron-sites, and high gas uptake under low pressure settings. |
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Bibliography: | Electronic supplementary information (ESI) available: Experimental procedures, characterization methods, and gas sorption studies. See DOI 10.1039/c2ce26487k |
ISSN: | 1466-8033 |
DOI: | 10.1039/c2ce26487k |