Gold nanoparticles-catalyzed activation of 1,2-disilanes: hydrolysis, silyl protection of alcohols and reduction of tert-benzylic alcoholsElectronic supplementary information (ESI) available: Spectroscopic data for all products (1H, 13C NMR). See DOI: 10.1039/c2cc35116a

Gold nanoparticles supported on TiO 2 catalyze under mild conditions the activation of a series of 1,2-disilanes towards hydrolysis and alcoholysis, with concomitant evolution of H 2 gas. For the case of tert -benzyl alcohols, the main or only pathway is reduction to the corresponding alkanes. Gold...

Full description

Saved in:
Bibliographic Details
Main Authors Gryparis, Charis, Stratakis, Manolis
Format Journal Article
LanguageEnglish
Published 08.10.2012
Online AccessGet full text

Cover

More Information
Summary:Gold nanoparticles supported on TiO 2 catalyze under mild conditions the activation of a series of 1,2-disilanes towards hydrolysis and alcoholysis, with concomitant evolution of H 2 gas. For the case of tert -benzyl alcohols, the main or only pathway is reduction to the corresponding alkanes. Gold nanoparticles supported on TiO 2 catalyse the dehydrogenative hydrolysis and alcoholysis of 1,2-disilanes under mild conditions.
Bibliography:1
13
10.1039/c2cc35116a
C NMR). See DOI
H
Electronic supplementary information (ESI) available: Spectroscopic data for all products
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc35116a