Accelerating the initial rate of hydrolysis of methyl parathion with laser excitation using monolayer protected 10 nm Au nanoparticles capped with a Cu(bpy) catalystElectronic supplementary information (ESI) available: Synthesis of compounds 14 and details on the kinetic experiments. See DOI: 10.1039/c2cc30850aThis work received support from the Defense Threat Reduction Agency-Joint Science and Technology Office for Chemical and Biological Defense (MIPR #B102405M and B112542M)

Using a low power green laser, we have demonstrated a rate acceleration of 2-fold for the hydrolysis of methyl parathion by irradiating the plasmon absorption band of Au nanoparticles capped with a Cu(bpy) catalyst. We show a rate acceleration for the hydrolysis of methyl parathion when irradiating...

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Bibliographic Details
Main Authors Trammell, Scott A, Nita, Rafaela, Moore, Martin, Zabetakis, Dan, Chang, Eddie, Knight, D. Andrew
Format Journal Article
LanguageEnglish
Published 28.03.2012
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Summary:Using a low power green laser, we have demonstrated a rate acceleration of 2-fold for the hydrolysis of methyl parathion by irradiating the plasmon absorption band of Au nanoparticles capped with a Cu(bpy) catalyst. We show a rate acceleration for the hydrolysis of methyl parathion when irradiating the plasmon absorption band of Au nanoparticles capped with a Cu(bpy) catalyst.
Bibliography:Electronic supplementary information (ESI) available: Synthesis of compounds
14
and details on the kinetic experiments. See DOI
This work received support from the Defense Threat Reduction Agency-Joint Science and Technology Office for Chemical and Biological Defense (MIPR #B102405M and B112542M).
10.1039/c2cc30850a
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc30850a