Growth of non-branching Ag nanowires via ion migrational-transport controlled 3D electrodepositionElectronic supplementary information (ESI) available: Details of experimental procedure, TEM images (Fig. S1), simulation parameter and the calculated results (Fig. S2 and S3). See DOI: 10.1039/c1ce05686g

Non-branching twinned Ag nanowires have been synthesized within a three-dimensional electrochemical deposition system by using a non-supporting electrolyte and an unusually high over-potential. The branching rate of the Ag nanowires is significantly decreased under the interactions of a strong appli...

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Bibliographic Details
Main Authors Ding, Chunhua, Tian, Cuifeng, Krupke, Ralph, Fang, Jixiang
Format Journal Article
LanguageEnglish
Published 11.01.2012
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Summary:Non-branching twinned Ag nanowires have been synthesized within a three-dimensional electrochemical deposition system by using a non-supporting electrolyte and an unusually high over-potential. The branching rate of the Ag nanowires is significantly decreased under the interactions of a strong applied potential and the low concentration electrolyte, in which an ion migrational-transport controlled 3D electrochemical growth is created. Additionally, according to finite-element simulations, a high density growth of Ag nanowires originating from the high over-potential creates a planar growth front, resulting in a small probability of the branching growth. Non-branching Ag nanowires have been synthesized within a three-dimensional electrochemical deposition by using a strong applied-potential and low concentration electrolyte.
Bibliography:Electronic supplementary information (ESI) available: Details of experimental procedure, TEM images (Fig. S1), simulation parameter and the calculated results (Fig. S2 and S3). See DOI
10.1039/c1ce05686g
ISSN:1466-8033
DOI:10.1039/c1ce05686g