Temperature-directed structural recurrence in low-symmetric Co(ii) complexes and nanocrystalsElectronic supplementary information (ESI) available: Crystallographic data; PXRD, CD, TGA, and temperature dependence of dielectric constants. CCDC 848323848325. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1cc16336a
Low-symmetric complexes {[Co( 2 -L)(H 2 O) 2 ]H 2 O} n ( 1 ) and {[Co( 3 -L)(H 2 O)]0.5H 2 O} n ( 2 ) and corresponding nanocrystals were obtained, which exhibit structural recurrence behaviour at various temperatures as well as changes of chiral, nonlinear optical and ferroelectric properties. Low-...
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| Main Authors | , , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
12.12.2011
|
| Online Access | Get full text |
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| Summary: | Low-symmetric complexes {[Co(
2
-L)(H
2
O)
2
]H
2
O}
n
(
1
) and {[Co(
3
-L)(H
2
O)]0.5H
2
O}
n
(
2
) and corresponding nanocrystals were obtained, which exhibit structural recurrence behaviour at various temperatures as well as changes of chiral, nonlinear optical and ferroelectric properties.
Low-symmetric Co(
ii
) complexes and nanocrystals exhibiting a just opposite structural recurrence pathway have been reported for the first time. |
|---|---|
| Bibliography: | 848323848325 For ESI and crystallographic data in CIF or other electronic format see DOI Electronic supplementary information (ESI) available: Crystallographic data; PXRD, CD, TGA, and temperature dependence of dielectric constants. CCDC 10.1039/c1cc16336a |
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c1cc16336a |