An unprecedented (5,12)-connected 3D self-penetrating metal-organic framework based on dinuclear barium clusters as building blocksElectronic supplementary information (ESI) available: X-Ray crystallographic file for compound 1 in CIF format, experimental section, additional structural figures, and physical characterizations. CCDC reference numbers 783475. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0ce00622j

An unprecedented binodal (5,12)-connected 3D self-penetrating metal-organic framework was first assembled from dinuclear barium clusters as 12-connected nodes and flexible ligands 4,4′-sulfonyldibenzoate as 5-connected nodes, and it represents the highest connected self-penetrating topology presentl...

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Main Authors Xiao, Dongrong, Chen, Haiyan, Zhang, Guangju, Sun, Dianzhen, He, Jianghong, Yuan, Ruo, Wang, Enbo
Format Journal Article
LanguageEnglish
Published 20.12.2010
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Summary:An unprecedented binodal (5,12)-connected 3D self-penetrating metal-organic framework was first assembled from dinuclear barium clusters as 12-connected nodes and flexible ligands 4,4′-sulfonyldibenzoate as 5-connected nodes, and it represents the highest connected self-penetrating topology presently known for metal-organic frameworks. The first twelve-connected self-penetrating network, which represents the highest connected topology presently known for the entangled system, is reported.
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For ESI and crystallographic data in CIF or other electronic format see DOI
in CIF format, experimental section, additional structural figures, and physical characterizations. CCDC reference numbers
783475
Electronic supplementary information (ESI) available: X-Ray crystallographic file for compound
10.1039/c0ce00622j
ISSN:1466-8033
DOI:10.1039/c0ce00622j