Tin-free radical cyclization reactions initiated by visible light photoredox catalysisElectronic supplementary information (ESI) available: Experimental procedures, 1H and 13C NMR spectra for all new compounds. See DOI: 10.1039/c0cc00981d
Herein, we report an advancement in the application of visible light photoredox catalysts in a classic free radical mediated reaction, cyclization onto unactivated π-systems. The reactive radical intermediate is generated by the single electron reduction of an activated C-Br bond by an electron-rich...
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Main Authors | , , , , |
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Format | Journal Article |
Language | English |
Published |
29.06.2010
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Online Access | Get full text |
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Summary: | Herein, we report an advancement in the application of visible light photoredox catalysts in a classic free radical mediated reaction, cyclization onto unactivated π-systems. The reactive radical intermediate is generated by the single electron reduction of an activated C-Br bond by an electron-rich redox catalyst afforded by a visible light induced catalytic cycle.
An advancement in the application of visible light photoredox catalysts in a classic free radical mediated reaction, cyclization onto unactivated π-systems. |
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Bibliography: | 1 13 C NMR spectra for all new compounds. See DOI H and 10.1039/c0cc00981d Electronic supplementary information (ESI) available: Experimental procedures |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c0cc00981d |