Combining halogen bonding and chirality in a two-dimensional organic metal (EDT-TTF-I2)2(D-camphorsulfonate)·H2OElectronic supplementary information (ESI) available: Crystallographic data for I and Fig. S1-S2. CCDC 768025. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0cc00175a

A chiral organic conductor with metallic conductivity has been obtained by electrocrystallisation of a diiodotetrathiafulvalene derivative and enantiopure D -camphorsulfonate anion, associated in the solid state by halogen bonding interactions. A chiral, 2D organic metal is described, associating th...

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Bibliographic Details
Main Authors Brezgunova, Mariya, Shin, Kyung-Soon, Auban-Senzier, Pascale, Jeannin, Olivier, Fourmigué, Marc
Format Journal Article
LanguageEnglish
Published 14.06.2010
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Summary:A chiral organic conductor with metallic conductivity has been obtained by electrocrystallisation of a diiodotetrathiafulvalene derivative and enantiopure D -camphorsulfonate anion, associated in the solid state by halogen bonding interactions. A chiral, 2D organic metal is described, associating through halogen bonding interactions, the enantiopure D -camphorsulfonate anion and a diiodotetrathiafulvalene.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
and Fig. S1-S2. CCDC
768025
10.1039/c0cc00175a
I
Electronic supplementary information (ESI) available: Crystallographic data for
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc00175a