Synthesis and characterization of a high-valent heterobimetallic [CuIII(μ-O)2NiIII]2+ core involving nucleophilic oxo groups

A heterobimetallic CuNi bis(μ-oxo) diamond core is shown to possess nucleophilic oxo groups, and has been demonstrated for the first time as a viable intermediate during the deformylation of fatty aldehydes by cyanobacterial aldehyde decarbonylase.

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 52; no. 21; pp. 5622 - 5626
Main Authors Kundu, Subrata, Pfaff, Florian Felix, Miceli, Enrico, Zaharieva, Ivelina, Herwig, Christian, Yao, Shenglai, Farquhar, Erik R., Kuhlmann, Uwe, Bill, Eckhard, Hildebrandt, Peter, Dau, Holger, Driess, Matthias, Limberg, Christian, Ray, Kallol
Format Journal Article
LanguageEnglish
Published 15.04.2013
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Summary:A heterobimetallic CuNi bis(μ-oxo) diamond core is shown to possess nucleophilic oxo groups, and has been demonstrated for the first time as a viable intermediate during the deformylation of fatty aldehydes by cyanobacterial aldehyde decarbonylase.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201300861