Chlorido(2-{(2-hydroxyethyl)[tris(hydroxymethyl)methyl]amino}ethanolato-κ5 N,O,O′,O′′,O′′′)copper(II)
The crystal structure of the title complex features O—H⋯O hydrogen bonds, which form (8), (16), (20) and (22) ring motifs. The title complex, [Cu(C 8 H 18 NO 5 )Cl] or [Cu(H 4 bis-tris)Cl], was obtained starting from the previously reported [Cu(H 5 bis-tris)Cl]Cl compound. The deprotonation of the...
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| Published in | IUCrData Vol. 9; no. Pt 5 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
International Union of Crystallography
24.05.2024
|
| Subjects | |
| Online Access | Get full text |
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| Summary: | The crystal structure of the title complex features O—H⋯O hydrogen bonds, which form
(8),
(16),
(20) and
(22) ring motifs.
The title complex, [Cu(C
8
H
18
NO
5
)Cl] or [Cu(H
4
bis-tris)Cl], was obtained starting from the previously reported [Cu(H
5
bis-tris)Cl]Cl compound. The deprotonation of the aminopolyol ligand H
5
bis-tris {[bis(2-hydroxyethyl)amino]tris(hydroxymethyl)methane, C
8
H
19
NO
5
} promotes the formation of a very strong O—H⋯O intermolecular hydrogen bond, characterized by an H⋯O separation of 1.553 (19) Å and an O—H⋯O angle of 178 (4)°. The remaining hydroxy groups are also engaged in hydrogen bonds, forming
R
2
2
(8),
R
4
4
(16),
R
4
4
(20) and
R
4
4
(22) ring motifs, which stabilize the triperiodic supramolecular network. |
|---|---|
| ISSN: | 2414-3146 |
| DOI: | 10.1107/S2414314624004395 |