Synthesis and characterization of ZrFe 2 O 4 @SiO 2 @Ade-Pd as a novel, recyclable, green, and versatile catalyst for Buchwald-Hartwig and Suzuki-Miyaura cross-coupling reactions

This work presents the simple synthesis of a green and novel Palladium based magnetic nanocatalyst with effective catalytic properties and reusability. These heterogeneous catalysts were prepared by the anchoring of Pd(0) on the surface of ZrFe O MNPs coated with a di-substituted adenine (Ade) compo...

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Bibliographic Details
Published inScientific reports Vol. 13; no. 1; p. 14728
Main Authors Saadh, Mohamed J, Khasawneh, Hussam Elddin Nabieh, Ortiz, Geovanny Genaro Reivan, Ahsan, Muhammad, Sain, Dinesh Kumar, Yusuf, Kareem, Sillanää, Mika, Iqbal, Amjad, Akhavan-Sigari, Reza
Format Journal Article
LanguageEnglish
Published England 07.09.2023
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Summary:This work presents the simple synthesis of a green and novel Palladium based magnetic nanocatalyst with effective catalytic properties and reusability. These heterogeneous catalysts were prepared by the anchoring of Pd(0) on the surface of ZrFe O MNPs coated with a di-substituted adenine (Ade) compound as a green linker. The as-synthesized ZrFe O @SiO @Ade-Pd MNPs were methodically characterized over different physicochemical measures like VSM, EDX, Map, SEM, TEM, ICP, and FT-IR analysis. The catalytic activity of ZrFe O @SiO @Ade-Pd was carefully examined for the room-temperature Carbon-Carbon coupling reaction in acetonitrile as a solvent. It is worth noting that the synthesized solid catalyst can be easily recovered with a bar magnet and reused for five cycles without decrease of catalytic activity.
ISSN:2045-2322