Polyethyleneimine-reinforced Sn/Cu foam dendritic self-supporting catalytic cathode for CO 2 reduction to HCOOH

• Published in: Chemosphere (Oxford) Vol. 301; p. 134704
• Main Authors: Yan, Yanjun, Peng, Yiyin, Song, Yuchao, Wang, Ruiyun, Wang, Hui, Bian, Zhaoyong
• Format: Journal Article
• Language: English
• Published: England 26.04.2022
• Subjects: Polyethyleneimine; Tin-on-Cu foam; Electrochemical reduction of CO; Electrodeposition; Formate
• ISSN: 1879-1298

In this work, a novel catalytic cathode of polyethyleneimine (PEI)-Sn/Cu foam with dendritic structure was prepared by electrodeposition and impregnation. It was used in the electrocatalytic reduction of CO to HCOOH, and its performance in this process was evaluated. At -0.97 V vs. RHE, the faradaic efficiency and current density reached 92.3% and 57.1 mA cm , respectively, in a 0.5 M KHCO electrolyte. The HCOOH production rate reached 890.4 μmol h  cm , which exceeds those for most reported Sn catalysts. Density functional theory calculations showed that use of Sn/Cu foam is more conducive to HCOOH formation than use of Cu or Sn alone, and *OCHO is the main intermediate in HCOOH formation. The results of OH adsorption experiments confirmed that the introduction of PEI enhanced the catalytic capacity of the Sn/Cu foam, stabilized CO · intermediates, and promoted HCOOH generation. These results will provide an attractive strategy for developing efficient catalysts with excellent activities and stabilities for CO electroreduction.