Electrochemical determination of dinitolmide in poultry product samples using a highly sensitive Mn 2 O 3 /MCNTs-NPs carbon paste electrode aided by greenness assessment tools

• Published in: Food chemistry Vol. 382; p. 131702
• Main Authors: Kelani, Khadiga M, Abdel-Raoof, Ahmed M, Ashmawy, Ashraf M, Omran, Gamal A, Morshedy, Samir, Wafaa Nassar, Ahmed M, Talaat, Wael, Elgazzar, Elsayed
• Format: Journal Article
• Language: English
• Published: England 15.07.2022
• Subjects: Carbon; Dinitolmide; Electrochemical Techniques; Electrodes; Poultry Products; Cuts-up chicken meat, egg; MnO/MCNTs-NPs nanostructure; Green assessment; Square wave voltammetry; Dinitolmide
• ISSN: 1873-7072

In this paper, chemically modified carbon paste Mn O /MCNTs-NPs electrode for estimation of dinitolmide (DOM) utilizing square wave voltammetry method (SWV) was developed. The study investigated the electrochemical behavior of DOM, and the morphology of the modified electrode was evaluated by Scanning Electron Microscope (SEM) and Transmission Electron Microscope (TEM). The voltammetric behavior of DOM at modified electrode was recorded at a scan rate of 100 mVs against Ag/AgCl reference electrode in phosphate buffer pH 4.0 within linearity range 2-12 µM, LOQ, and LOD of 1.8 and 0.594 µM, respectively, with average % recovery of (100.89 ± 0.795). GAPI and Analytical Eco-Scale tools were applied for greenness assessment. Specificity and interference study was valid for the proposed method; allowing DOM to be determined in its acidic degradation and its major interference drug. The proposed method was successfully employed to quantify DOM in bulk powder, egg, and frozen cuts-up chicken muscle samples.