Biohydrogen production from catalytic conversion of food waste via steam and air gasification using eggshell- and homo-type Ni/Al 2 O 3 catalysts
Steam and air gasification with 5 wt% Ni/Al O eggshell (Ni-EG) and homo (Ni-H) catalysts were performed for the first time to produce biohydrogen from food waste. The steam gasification produced comparably higher gas yield than air gasification. In non-catalytic experiments, steam gasification gener...
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Published in | Bioresource technology Vol. 320; no. Pt B; p. 124313 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
01.01.2021
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Subjects | |
Online Access | Get full text |
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Summary: | Steam and air gasification with 5 wt% Ni/Al
O
eggshell (Ni-EG) and homo (Ni-H) catalysts were performed for the first time to produce biohydrogen from food waste. The steam gasification produced comparably higher gas yield than air gasification. In non-catalytic experiments, steam gasification generated a higher volume percent of H
, whereas more CO, CO
, CH
, and C
-C
were produced in air gasification. Ni-EG demonstrated higher potential to obtain H
-rich gases with a low C
-C
content compared to that obtained by Ni-H, particularly in steam gasification at 800 °C, which produced gaseous products with 59.48 vol% H
. The long-term activity of both catalysts in steam gasification was evaluated, and Ni-EG exhibited higher stability than Ni-H. The ideal distribution of Ni species on the outer region of γ-Al
O
pellets in Ni-EG resulted in higher activity, stability, and selectivity than Ni-H in both steam and air gasification. |
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ISSN: | 1873-2976 |