Embedding hexanuclear tantalum bromide cluster {Ta 6 Br 12 } into SiO 2 nanoparticles by reverse microemulsion method
Hexanuclear tantalum bromide cluster units [{Ta Br }L ] (i = inner, a = apical, L = ligand OH or H O) are embedded into SiO nanoparticles by a reverse microemulsion (RM) based method. [{Ta Br }Br (H O) ]· H O (noted TBH) and tetraethyl orthosilicate (TEOS) are used as the starting cluster compound a...
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Published in | Heliyon Vol. 4; no. 6; p. e00654 |
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Main Authors | , , , , , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
01.06.2018
|
Subjects | |
Online Access | Get full text |
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Summary: | Hexanuclear tantalum bromide cluster units [{Ta
Br
}L
] (i = inner, a = apical, L = ligand OH or H
O) are embedded into SiO
nanoparticles by a reverse microemulsion (RM) based method. [{Ta
Br
}Br
(H
O)
]·
H
O (noted TBH) and tetraethyl orthosilicate (TEOS) are used as the starting cluster compound and the precursor of SiO
, respectively. The RM system in this study consists of the
-heptane (oil phase), Brij L4 (surfactants), ethanol, TEOS, ammonia solution and TBH aqueous sol. The size and morphology of the product namely {Ta
Br
}@SiO
nanoparticles are analyzed by HAADF-STEM and EDS mappings. The presence and integrity of {Ta
Br
} in the SiO
nanoparticles are evidenced by EDS mapping, ICP-OES/IC and XPS analysis. The optical properties of {Ta
Br
}@SiO
nanoparticles are analyzed by diffuse reflectance UV-vis spectroscopy, further evidencing the integrity of the embedded {Ta
Br
} and revealing their oxidation state. Both {Ta
Br
}
and {Ta
Br
}
are found in SiO
nanoparticles, but the latter is much more stable than the former. The by-products in this RM-based synthesis, as well as their related factors, are also discussed. |
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ISSN: | 2405-8440 2405-8440 |