Exploring optoelectronic properties and mechanisms of layered ferroelectric K 4 Nb 6 O 17 nanocrystalline films and nanolaminas
Two-dimensional layered K Nb O (KN) was easily formed as a secondary phase caused by the volatilization of alkali metal ions, when preparing ferroelectric K Na NbO based ceramics and films. In this work, it was believed that KN film is with weak ferroelectricity and has a little effect on the ferroe...
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Published in | Scientific reports Vol. 7; no. 1; p. 1883 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
15.05.2017
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Online Access | Get full text |
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Summary: | Two-dimensional layered K
Nb
O
(KN) was easily formed as a secondary phase caused by the volatilization of alkali metal ions, when preparing ferroelectric K
Na
NbO
based ceramics and films. In this work, it was believed that KN film is with weak ferroelectricity and has a little effect on the ferroelectric properties of K
Na
NbO
based films. Moreover, temperature dependent (77-500 K) dielectric functions of KN film have been firstly extracted by fitting ellipsometric spectra with the Adachi dielectric function model and a four-phase layered model. The high-frequency dielectric constant linearly increases and optical band gap slightly decreases with increasing the temperature. We also research its photoelectrochemical properties and its application in high-efficient light-induced H
evolution. In addition, X-ray photoelectron spectroscopy, Raman scattering, temperature dependent transmittance and infrared reflectance spectra, and first-principles calculation were conjointly performed to further reveal the intrinsic optoelectronic features and relevant mechanisms of KN. |
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ISSN: | 2045-2322 |