Bi10{RuPPh3}3-: Paramagnetic 13-Vertex Polybismuthide Heteroanion

Ru(PPh3)3Cl2 reacts with Binn- from an ethylenediamine (en) solution of K5Bi4 to yield a new architype of 13-vertex [Bi10{RuPPh3}3]- (1) composed of unprecedented incomplete cuboidal Bi73- and triangular Bi33- held together by {RuPPh3}2+.Ru(PPh3)3Cl2 reacts with Binn- from an ethylenediamine (en) so...

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Published inInorganic chemistry Vol. 63; no. 43; p. 20088
Main Authors Wang, Yueyue, Li, Yankai, Sang, Ruili, Xu, Li
Format Journal Article
LanguageEnglish
Published 28.10.2024
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Summary:Ru(PPh3)3Cl2 reacts with Binn- from an ethylenediamine (en) solution of K5Bi4 to yield a new architype of 13-vertex [Bi10{RuPPh3}3]- (1) composed of unprecedented incomplete cuboidal Bi73- and triangular Bi33- held together by {RuPPh3}2+.Ru(PPh3)3Cl2 reacts with Binn- from an ethylenediamine (en) solution of K5Bi4 to yield a new architype of 13-vertex [Bi10{RuPPh3}3]- (1) composed of unprecedented incomplete cuboidal Bi73- and triangular Bi33- held together by {RuPPh3}2+.
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ISSN:1520-510X
1520-510X
DOI:10.1021/acs.inorgchem.4c01287