Tin-Mediated Route to Polytungstates of Rh super(II) and Pd super(II)
Three polyoxotungstates of Sn super(II), Pd super(II), and Rh super(II), Na sub(8)[H sub(2)SnW sub(1 2)O sub(42)].nH sub(2)O [1, n = 22.75 (1a) and n = 31.10 (1b)], Na sub(2)K(H)[Pd(H sub(2)O) sub(4)][H sub(2)W sub(12)O sub(48){Pd(H sub(2)O) sub(3) } sub(2)].10H sub(2)O (2), and Na sub(8)[Rh sub(2)(...
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Published in | European journal of inorganic chemistry Vol. 2013; no. 10-11; pp. 1772 - 1779 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
01.04.2013
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Subjects | |
Online Access | Get full text |
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Summary: | Three polyoxotungstates of Sn super(II), Pd super(II), and Rh super(II), Na sub(8)[H sub(2)SnW sub(1 2)O sub(42)].nH sub(2)O [1, n = 22.75 (1a) and n = 31.10 (1b)], Na sub(2)K(H)[Pd(H sub(2)O) sub(4)][H sub(2)W sub(12)O sub(48){Pd(H sub(2)O) sub(3) } sub(2)].10H sub(2)O (2), and Na sub(8)[Rh sub(2)(H sub(2 )O) sub(2)(W sub(5)O sub(18)) sub(2)].21.25H sub(2)O (3) were obtained. The complexes were characterized by X-ray analysis, solid-state super(1)H NMR spectroscopy, IR spectroscopy, thermogravimetric analysis, and elemental analysis. Polyoxotungstates of Sn super(II), Pd super(II), and Rh super(II), Na sub(8)[H sub(2)SnW sub(1 2)O sub(42)].nH sub(2)O, Na sub(2)K(H)[Pd(H sub(2)O) sub(4)][H sub(2)W sub(12)O sub(48){Pd(H sub(2)O) sub(3) } sub(2)].10H sub(2)O, and Na sub(8)[Rh sub(2)(H sub(2 )O) sub(2)(W sub(5)O sub(18)) sub(2)].nH sub(2)O, were obtained and characterized by X-ray analysis and solid-state super(1)H NMR spectroscopy. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 content type line 23 ObjectType-Feature-2 |
ISSN: | 1434-1948 1099-0682 |
DOI: | 10.1002/ejic.201201162 |