Efficient optical resolution of water-soluble self-assembled tetrahedral M sub(4)L sub(6) cages with 1,1'-bi-2-naphthol

In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe sub(4)L sub(6)] super(4 -) was successfully resolved into their Delta Delta Delta Delta and Lambda Lambda Lambda Lambda enantiomers by (R)-/(S)-1,1'-bi-2-naphtho l. The enantiomeric excess of the resolved Fe(ii) cage was...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 97; pp. 15301 - 15304
Main Authors Wan, Shigang, Lin, Li-Rong, Zeng, Lili, Lin, Yiji, Zhang, Hui
Format Journal Article
LanguageEnglish
Published 01.11.2014
Subjects
Cages
Enantiomers
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Summary:In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe sub(4)L sub(6)] super(4 -) was successfully resolved into their Delta Delta Delta Delta and Lambda Lambda Lambda Lambda enantiomers by (R)-/(S)-1,1'-bi-2-naphtho l. The enantiomeric excess of the resolved Fe(ii) cage was 99%.
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SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc04145c