Highly monodisperse Pt(0)C NPs as highly efficient and reusable catalysts: the effect of the surfactant on their catalytic activities in room temperature dehydrocoupling of DMAB

• Published in: Catalysis science & technology Vol. 6; no. 6; pp. 1685 - 1692
• Main Authors: Celik, Betuel, Erken, Esma, Eris, Sinan, Yildiz, Yunus, Sahin, Birguetay, Pamuk, Handan, Sen, Fatih
• Format: Journal Article
• Language: English
• Published: 01.03.2016
• Subjects: Catalysis; Catalysts; Crystal structure; Hydrogen storage materials; Ligands; Nanoparticles; Nanostructure; X-ray photoelectron spectroscopy
• ISSN: 2044-4753; 2044-4761
• DOI: 10.1039/c5cy01371b

Addressed herein, we report the development of highly efficient and monodisperse Pt(0) nanoclusters for the dehydrocoupling of dimethylamine-borane (DMAB) which is considered to be one of the new hydrogen storage materials. The prepared Pt(0) nanoclusters were in situ generated for the first time from the reduction of PtCl4 and use of dipentylamine (DPA) and tripentylamine (TPA) ligands on activated carbon for the dehydrocoupling of dimethylamine-borane at room temperature and characterized by ICP-OES, XRD, TEM, HR-TEM, AFM, EDX, and XPS techniques. All the results show that highly crystalline and stable colloidal Pt(0)/DPAC and Pt(0)/TPAC nanoparticles have been formed and Pt(0)/DPAC and Pt(0)/TPAC were found to be two of the most active and long-lived catalysts with superior reusability performance in the dehydrocoupling of DMAB at room temperature.