Purification of rare-earth metals as the approach to improving properties of hard magnetic Nd sub(2)Fe sub(14)B-based materials
Purification of rare-earth metals, namely, Nd, Pr, Tb, Dy used in manufacturing Nd sub(2)Fe sub(14)B-based magnets was realized. The metals were purified by vacuum distillation/sublimation. Conditions of the process were optimized and the structure of distilled metals was studied. Distilled terbium...
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Published in | IOP conference series. Materials Science and Engineering Vol. 112; no. 1; pp. 12009 - 12015 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
01.01.2016
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Subjects | |
Online Access | Get full text |
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Summary: | Purification of rare-earth metals, namely, Nd, Pr, Tb, Dy used in manufacturing Nd sub(2)Fe sub(14)B-based magnets was realized. The metals were purified by vacuum distillation/sublimation. Conditions of the process were optimized and the structure of distilled metals was studied. Distilled terbium and dysprosium were used to prepare hydrides TbH2 and DyH2. Peculiarities of the decomposition of terbium and dysprosium hydrides were studied with the view of the use of the compounds as efficient additions, which allow the high- coercivity state of sintered magnets to be formed. Terbium hydride additions (to 4 wt %) favor the marked increase in the magnetization coercive force without excessive attenuation of the remanence ( sub(j) H sub(c) = 1940 kA/m, (BH sub(max)) = 292 kJ/m super(3)). Dysprosium hydride additions increase the stability of high-coercivity state ( sub(j) H sub(c) = 1310 kA/m, (BH sub(max)) = 322 kJ/m super(3) at 2 wt% DyH sub(2)). |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 content type line 23 ObjectType-Feature-2 |
ISSN: | 1757-8981 1757-899X |
DOI: | 10.1088/1757-899X/112/1/012009 |