A Complexation Study of 2,6-Bis(1-(p-tolyl)-1H-1,2,3-tria zol-4-yl)pyridine Using Single-Crystal X-ray Diffraction and TRLFS

• Published in: Inorganic chemistry Vol. 54; no. 15; pp. 7301 - 7308
• Main Authors: Kiefer, Claude, Wagner, Anna T, Beele, Bjorn B, Geist, Andreas, Panak, Petra J, Roesky, Peter W
• Format: Journal Article
• Language: English
• Published: 03.08.2015
• Subjects: Acetonitrile; Complexation; Diffraction; Lasers; Ligands; Samarium compounds; Single crystals; X-rays
• ISSN: 0020-1669
• DOI: 10.1021/acs.inorgchem.5b00803

To develop a selective ligand for the separation of lanthanides(III) and actinides(III) the coordination chemistry of the chelating N-donor ligand 2,6-bis(1-(p-tolyl)-1H-1,2,3-tria zol-4-yl)pyridine (BTTP) was investigated. The two isostructural lanthanide compounds [Ln(BTTP) sub(3)(OTf) sub(3)] (Ln = Eu (1), Sm (2); OTf = trifluoromethanesulfonate) were synthesized and fully characterized. The solid-state structures of both compounds were established by single-crystal X-ray diffraction. The complexation of Cm(III) and Eu(III) with BTTP in acetonitrile was studied using time-resolved laser fluorescence spectroscopy. With increasing BTTP concentration Cm(III) 1:2 and 1:3 complexes and Eu(III) 1:1 and 1:3 complexes are identified. The conditional stability constants of the 1:3 complex species with BTTP are log beta sub(3) = 14.0 for Cm(III) and log beta sub(3) = 10.3 for Eu(III). Both M(III) 1:3 complexes are prone to decomplexation with increasing acidity.