Effect of Mn addition on the thermal stability and magnetic properties of rapidly-quenched L1 sub(0) FePt alloys

• Published in: Intermetallics Vol. 65; pp. 81 - 87
• Main Authors: Crisan, O, Crisan, A D, Mercioniu, I, Pantelica, D, Pantelica, A, Vaucher, S, Nicula, R, Stir, M, Vasiliu, F
• Format: Journal Article
• Language: English
• Published: 01.01.2015
• Subjects: Alloys; Diffraction; Ferrous alloys; Intermetallics; Magnetic properties; Magnets; Manganese; Platinum compounds
• ISSN: 0966-9795
• DOI: 10.1016/j.intermet.2015.06.008

Nano-composite magnets with L1 sub(0) structure derived from binary FePt alloys and prepared as melt-spun ribbons are of current interest due to their higher operating temperature and the ability to be cast as a two-phase magnet with exchange spring magnetic properties, as both soft and hard magnetic phase may emerge from the same metastable precursor, i.e. the disordered cubic A1 phase. The present paper studies the effect of Mn addition on the thermal stability and phase structure, on the abundance of the hard magnetic phase and relative proportion of the soft ones, on the microstructure of the alloy as a function of temperature and on the overall magnetic properties. The interplay of the various magnetic sublattices in the ordering of the L1 sub(0) phases as a consequence of introducing antiferromagnetically coupled Mn atoms in the alloy composition is discussed and interpreted in terms of microstructural changes induced by this addition as revealed by high resolution transmission electron microscopy and X-ray diffraction. The temperature evolution of the phase composition and structural parameters is monitored using synchrotron radiation powder diffraction, while the compositional aspects are investigated using proton-induced X-ray emission and energy dispersive X-ray spectroscopy. Magnetic measurements reveal the magnetic parameters of interest (coercivity, remanence, Curie temperature, saturation magnetization), as well as the exchange-coupled two-phase nature of these magnets and provide information that hints at possible spin reorientation transitions in the Mn-containing planes of the L1 sub(0) superlattice.