Chrysaorenes: assembling coronoid hydrocarbons viathe fold-in synthesis

Two coronoid hydrocarbons, [3]- and [4]chrysaorene were synthesized from fluorenophane precursors using the fold-in strategy. [3]Chrysaorene is a bowl-shaped fragment of the C sub(240)-I sub(h) fullerene, whereas [4]chrysaorene is planar and contains a unique large 24-membered internal ring. The chr...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 51; no. 82; pp. 15094 - 15097
Main Authors Majewski, Marcin A, Lis, Tadeusz, Cybinska, Joanna, Stepien, Marcin
Format Journal Article
LanguageEnglish
Published 01.01.2015
Subjects
Assembling
Fluorescence
Fragmentation
Fullerenes
Hydrocarbons
Magnetic properties
Precursors
Strategy
Synthesis
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Summary:Two coronoid hydrocarbons, [3]- and [4]chrysaorene were synthesized from fluorenophane precursors using the fold-in strategy. [3]Chrysaorene is a bowl-shaped fragment of the C sub(240)-I sub(h) fullerene, whereas [4]chrysaorene is planar and contains a unique large 24-membered internal ring. The chrysaorenes show geometry-dependent magnetic properties and are strongly fluorescent.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc06046j