Catalase-like activity of the polyoxovanadate anion [Mn super(IV)V sub(13)O sub(38)] super(7-): a mechanistic study

The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water (TON > 200) by a Mn super(IV/II) cycle, which operates viaquick formation of diperoxovanadate at the surface of 1.

Saved in:
Bibliographic Details
Published inCatalysis science & technology Vol. 2; no. 11; pp. 2224 - 2226
Main Authors Chakrabarty, Sanchita, Banerjee, Rupendranath
Format Journal Article
LanguageEnglish
Published 01.01.2012
Subjects
Acetates
Anions
Buffers
Catalysis
Disproportionation
Formations
Hydrogen peroxide
Surface chemistry
Online AccessGet full text

Cover

Abstract The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water (TON > 200) by a Mn super(IV/II) cycle, which operates viaquick formation of diperoxovanadate at the surface of 1.
AbstractList The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water (TON > 200) by a Mn super(IV/II) cycle, which operates viaquick formation of diperoxovanadate at the surface of 1.
Author Chakrabarty, Sanchita
Banerjee, Rupendranath
Author_xml – sequence: 1
  givenname: Sanchita
  surname: Chakrabarty
  fullname: Chakrabarty, Sanchita
– sequence: 2
  givenname: Rupendranath
  surname: Banerjee
  fullname: Banerjee, Rupendranath
BookMark eNqVi0tLw0AUhQepYNVu_AV3mSyi88ijcVsUXYgb6UakXKe3dHQ6E3snxfx7gxT3ns354DvnXExCDCTElZLXSpr2xmo7aKlqgydiqmVZFmVTq8kfV-ZMzJg_5JiyVXKup4IXmNAjU-HdJwHa5A4uDRA3kLYEXfRD_I4HDLjGNPrgYoDXpwDcd7TPHpf5csT3TJn8-RfMPH87yqbIbwFhR3Y7_jg5C5z69XApTjfomWbHvhDZ_d3L4qHo9vGrJ06rnWNL3mOg2PNKNbWWVSOr1vxj-gMG91Vh
ContentType Journal Article
DBID 7SR
8BQ
8FD
JG9
DOI 10.1039/c2cy20163a
DatabaseName Engineered Materials Abstracts
METADEX
Technology Research Database
Materials Research Database
DatabaseTitle Materials Research Database
Engineered Materials Abstracts
Technology Research Database
METADEX
DatabaseTitleList Materials Research Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 2044-4761
EndPage 2226
GroupedDBID -JG
0-7
0R~
705
7SR
8BQ
8FD
AAIWI
AAJAE
AANOJ
AARTK
AAWGC
AAXHV
ABASK
ABDVN
ABEMK
ABJNI
ABPDG
ABRYZ
ABXOH
ACAYK
ACGFS
ACIWK
ACLDK
ADMRA
ADSRN
AEFDR
AENEX
AENGV
AESAV
AETIL
AFLYV
AFOGI
AFVBQ
AGEGJ
AGRSR
AGSTE
AHGCF
AKBGW
ALMA_UNASSIGNED_HOLDINGS
ANBJS
ANUXI
APEMP
ASKNT
AUDPV
AUNWK
BLAPV
BSQNT
C6K
EBS
ECGLT
EE0
EF-
GGIMP
H13
HZ~
H~N
J3G
J3H
J3I
JG9
O-G
O9-
OK1
R7G
RAOCF
RCNCU
RNS
RPMJG
RRC
RSCEA
RVUXY
SKA
SKF
SKH
SKJ
SKM
SKR
SKZ
SLC
SLF
SLH
SMJ
ID FETCH-proquest_miscellaneous_17620570593
ISSN 2044-4753
IngestDate Sat Aug 17 03:32:34 EDT 2024
IsPeerReviewed true
IsScholarly true
Issue 11
Language English
LinkModel OpenURL
MergedId FETCHMERGED-proquest_miscellaneous_17620570593
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
content type line 23
ObjectType-Feature-2
PQID 1762057059
PQPubID 23500
ParticipantIDs proquest_miscellaneous_1762057059
PublicationCentury 2000
PublicationDate 20120101
PublicationDateYYYYMMDD 2012-01-01
PublicationDate_xml – month: 01
  year: 2012
  text: 20120101
  day: 01
PublicationDecade 2010
PublicationTitle Catalysis science & technology
PublicationYear 2012
SSID ssj0000491082
Score 3.952486
Snippet The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water...
SourceID proquest
SourceType Aggregation Database
StartPage 2224
SubjectTerms Acetates
Anions
Buffers
Catalysis
Disproportionation
Formations
Hydrogen peroxide
Surface chemistry
Title Catalase-like activity of the polyoxovanadate anion [Mn super(IV)V sub(13)O sub(38)] super(7-): a mechanistic study
URI https://search.proquest.com/docview/1762057059
Volume 2
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1bS8MwFA5zPuiLeMU7ERxsSHVNm3b1TedlXuZAtjkQGW2XonO24lpx_npP0naLF3D6UpKshAPft5zk9JwvCG0zzVOJ5xqKZ3i2oncYURzTgr87NTUdWM06Li9wrl4ZlYZ-3qKtTGYgZS1FobPrvv9YV_IfVGEMcOVVsn9AdjgpDEAb8IUnIAzPsTAu89gLuCGl9_AYy2K8JhkWogAq6A2Ct4DfmsyP9Tu2L6Cmh1V_px89c6xKZ80csZrQdbhgE4-61pIOFzS3cvRo-Kqp8AFRG_3EeL2wkHiW9Gm7klFC5yQtGeLsCr-F8EcJBXG6GdDv_iEcxQdsn7104zSh64jf1Ate1Q7v5TCFyPdIwxRiNSNFXVd0M1YG3mXyWKzGni7HRGadKq-tJK62Tvw0dI0ffUBR4xKqLnEHYIehSZ4u_bp_VWufNC4v2_XjVn0CTRLTojSLJg8uDk9vhgE6ODqpRXHZ2ND0VN5Ws_ZG039z4mJnUp9FM8mRAh_E_JhDGebPo6lyepPfAup_4glOeYIDDwNP8BeeYMETfFv1sYA-f9YsNKHp5FWtUBMNrVS4S340lcI-trHECCwYsYjyJ8f1ckVJrW6DNfwrEcAaRP22Cu4RNvH8qscllPUDny0jTBkhzILThGuXdFeFJum4TlErdVSbepSsoK1fp1sd4501ND0izzrKhi8R24BdX-hsJvh8ABlzXJQ
link.rule.ids 315,786,790,27955,27956
linkProvider Royal Society of Chemistry
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Catalase-like+activity+of+the+polyoxovanadate+anion+%5BMn+super%28IV%29V+sub%2813%29O+sub%2838%29%5D+super%287-%29%3A+a+mechanistic+study&rft.jtitle=Catalysis+science+%26+technology&rft.au=Chakrabarty%2C+Sanchita&rft.au=Banerjee%2C+Rupendranath&rft.date=2012-01-01&rft.issn=2044-4753&rft.eissn=2044-4761&rft.volume=2&rft.issue=11&rft.spage=2224&rft.epage=2226&rft_id=info:doi/10.1039%2Fc2cy20163a&rft.externalDBID=NO_FULL_TEXT
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2044-4753&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2044-4753&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2044-4753&client=summon