Catalase-like activity of the polyoxovanadate anion [Mn super(IV)V sub(13)O sub(38)] super(7-): a mechanistic study
The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water (TON > 200) by a Mn super(IV/II) cycle, which operates viaquick formation of diperoxovanadate at the surface of 1.
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Published in | Catalysis science & technology Vol. 2; no. 11; pp. 2224 - 2226 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
01.01.2012
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Subjects | |
Online Access | Get full text |
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Summary: | The anion [Mn super(IV)V sub(13)O sub(38)] super(7-), 1, in aqueous acetate buffer catalyses the disproportionation of hydrogen peroxide into oxygen and water (TON > 200) by a Mn super(IV/II) cycle, which operates viaquick formation of diperoxovanadate at the surface of 1. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 content type line 23 ObjectType-Feature-2 |
ISSN: | 2044-4753 2044-4761 |
DOI: | 10.1039/c2cy20163a |