Unexpected C&z.dbd; N bond formation via NaI-catalyzed oxidative de-tetra-hydrogenative cross-couplings between N,N-dimethyl aniline and sulfamides

A direct and convenient C&z.dbd; N bond formation reaction was reported, which was a de-tetra-hydrogenative cross-coupling (DTCC) reaction between N,N-dimethyl aniline and sulfamide under transition-metal-free conditions, and to give sulfonyl amidine derivatives in moderate to high yields.

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Bibliographic Details
Published inRSC advances Vol. 5; no. 62; pp. 50113 - 50117
Main Authors Zheng, Yang, Mao, Jincheng, Chen, Jie, Rong, Guangwei, Liu, Defu, Yan, Hong, Chi, Yongjian, Xu, Xinfang
Format Journal Article
LanguageEnglish
Published 01.06.2015
Subjects
Aniline
Bonding
Derivatives
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Summary:A direct and convenient C&z.dbd; N bond formation reaction was reported, which was a de-tetra-hydrogenative cross-coupling (DTCC) reaction between N,N-dimethyl aniline and sulfamide under transition-metal-free conditions, and to give sulfonyl amidine derivatives in moderate to high yields.
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ISSN:2046-2069
DOI:10.1039/c5ra06773a