Microfluidic Synthesis of Palladium Nanocrystals Assisted by Supercritical CO sub(2): Tailored Surface Properties for Applications in Boron Chemistry

On the surface: A library of organic-inorganic hybrid palladium nanocrystals was synthesized using continuous supercritical microfluidic technology. The nanocatalysts show moderate to excellent activities towards C sub(Ar)--B and C sub(Ar)--C sub(Ar) bond-forming reactions, thus illustrating the rel...

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Published inAngewandte Chemie International Edition Vol. 51; no. 34; pp. 8525 - 8528
Main Authors Gendrineau, Thomas, Marre, Samuel, Vaultier, Michel, Pucheault, Mathieu, Aymonier, Cyril
Format Journal Article
LanguageEnglish
Published 01.08.2012
Subjects
Bonding
Carbon dioxide
Microfluidics
Nanocrystals
Nanostructure
Palladium
Surface chemistry
Surface properties
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Summary:On the surface: A library of organic-inorganic hybrid palladium nanocrystals was synthesized using continuous supercritical microfluidic technology. The nanocatalysts show moderate to excellent activities towards C sub(Ar)--B and C sub(Ar)--C sub(Ar) bond-forming reactions, thus illustrating the relationship between surface properties and modulated catalytic activity.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201203083