Spectroscopy of ammonia in the range 6626-6805 cm super(-1): using temperature dependence towards a complete list of lower state energy transitions

Systematic analysis of the temperature dependence of the intensity ratio between already assigned and unassigned transitions enabled the determination of the most probable energy of the lower state of the unassigned transition. Such a procedure has been applied to transitions of super(14)NH sub(3) a...

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Bibliographic Details
Published inMolecular physics Vol. 112; no. 18; pp. 2476 - 2485
Main Authors Cacciani, P, Cermak, P, Cosleou, J, Romh, JEl, Hovorka, J, Khelkhal, M
Format Journal Article
LanguageEnglish
Published 17.09.2014
Subjects
Ammonia
Band spectra
Bands
Fourier transforms
Infrared
Spectra
Tasks
Temperature dependence
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Summary:Systematic analysis of the temperature dependence of the intensity ratio between already assigned and unassigned transitions enabled the determination of the most probable energy of the lower state of the unassigned transition. Such a procedure has been applied to transitions of super(14)NH sub(3) ammonia in the range 6626-6805 cm super(-1) between 130 and 300 K. This information is of great interest in the considerable task of the assignment of the complete 1.5 mu m infrared spectral range where combination and overtone vibrational bands are present. 2451 transitions have been observed at different temperatures. For 2133 the line strength and for 1956 transitions the values of lower state energies were derived. Our work was compared with recent Fourier transform study covering a larger energy range (6300-7000 cm super(-1)) with smaller temperature range (185-296 K)
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ISSN:0026-8976
1362-3028
DOI:10.1080/00268976.2014.924653