Reactivity of a fac-ReCl( alpha -diimine)(CO) sub(3) complex with an NAD super(+) model ligand toward CO sub(2) reduction

The reactivity of a rhenium complex containing an NAD super(+) model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO sub(2) reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle an...

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Published inChemical communications (Cambridge, England) Vol. 50; no. 6; pp. 728 - 730
Main Authors Matsubara, Yasuo, Hightower, Sean E, Chen, Jinzhu, Grills, David C, Polyansky, Dmitry E, Muckerman, James T, Tanaka, Koji, Fujita, Etsuko
Format Journal Article
LanguageEnglish
Published 01.12.2013
Subjects
Carbon dioxide
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Summary:The reactivity of a rhenium complex containing an NAD super(+) model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO sub(2) reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph sub(3)C super(+).
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
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ObjectType-Feature-1
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47699e