ExoMol line lists -- LI. Molecular line list for lithium hydroxide (LiOH)

A new molecular line list for lithium hydroxide (\(^{7}\)Li\(^{16}\)O\(^{1}\)H) covering wavelengths \(\lambda > 1 \mu\)m (the 0-10000 cm\(^{-1}\) range) is presented. The OYT7 line list contains over 331 million transitions between rotation-vibration energy levels with total angular momentum up...

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Bibliographic Details
Published inarXiv.org
Main Authors Owens, Alec, Wright, Sam O M, Pavlenko, Yakiv, Mitrushchenkov, Alexander, Koput, Jacek, Yurchenko, Sergei N, Tennyson, Jonathan
Format Paper
LanguageEnglish
Published Ithaca Cornell University Library, arXiv.org 07.08.2023
Subjects
Angular momentum
Celestial bodies
Dipole moments
Electron states
Energy levels
Extrasolar planets
Lithium hydroxides
Planetary atmospheres
Potential energy
Pressure dependence
Temperature dependence
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Summary:A new molecular line list for lithium hydroxide (\(^{7}\)Li\(^{16}\)O\(^{1}\)H) covering wavelengths \(\lambda > 1 \mu\)m (the 0-10000 cm\(^{-1}\) range) is presented. The OYT7 line list contains over 331 million transitions between rotation-vibration energy levels with total angular momentum up to \(J=95\) and is applicable for temperatures up to \(T\approx 3500\) K. Line list calculations are based on a previously published, high-level \textit{ab initio} potential energy surface and a newly computed dipole moment surface of the ground \(\tilde{X}\,^1\Sigma^+\) electronic state. Lithium-containing molecules are important in a variety of stellar objects and there is potential for LiOH to be observed in the atmospheres of exoplanets. This work provides the first, comprehensive line list of LiOH and will facilitate its future molecular detection. The OYT7 line list along with the associated temperature- and pressure-dependent opacities can be downloaded from the ExoMol database at www.exomol.com and the CDS astronomical database.
ISSN:2331-8422