Non-wovens carbon nanofibers doped and covered with carbon nanotubes as binderless hybridhierarchical electrode for lithium storage

This study is an investigation of a hybrid hierarchical electrode produced by electrospinning and chemical vapor deposition methods. The binderless hybrid hierarchical electrode is composed by carbon nanofibers with carbon nanotubes inside and outside the fibers. Single- walled or multi-walled carbo...

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Bibliographic Details
Published inOpen access journal of science and technology
Main Author Matsubara, Elaine Y
Format Journal Article
LanguageEnglish
Published Giza AgiAl Publishing House 01.01.2020
Subjects
Capacitance
Carbon
Carbon fibers
Chemical vapor deposition
Electrodes
Investigations
Lithium
Lithium-ion batteries
Manganese
Multi wall carbon nanotubes
Nanofibers
Nanoparticles
Nanotubes
Rechargeable batteries
Scanning electron microscopy
Spectroscopy
Vapors
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Summary:This study is an investigation of a hybrid hierarchical electrode produced by electrospinning and chemical vapor deposition methods. The binderless hybrid hierarchical electrode is composed by carbon nanofibers with carbon nanotubes inside and outside the fibers. Single- walled or multi-walled carbon nanotubesare present inside the nanofiber as a dopant and they are incorporated during the carbon nanofiber electrospun production. After that, multi-walled carbon nanotubes are grown onto the surface of the carbon nanofiber using chemical vapor deposition method.The suitability of carbon nanofibers for lithium storage applications was investigated by electrochemical methods using charge and discharge curves, cyclic voltammetry and impedance spectroscopy. The morphology of the flexible binderless hybrid hierarchical electrodes was investigated by scanning electron microscopy. The additional incorporation of oxide nanoparticles (manganese, zinc or both) by electrodeposition method are responsible to improve the specific capacitance of the electrode, showing new perspectives to use this electrodethis electrodeconfiguration to produce lightweight, flexible and conductiveonelectrode for lithium ion batteries without binder addition.
ISSN:2314-5234