Biomolecular l-tryptophan as a hole mediator anchored on g-C3N4 exhibits remarkably enhanced photocatalytic H2 evolution

• Published in: Catalysis science & technology Vol. 11; no. 14; pp. 4776 - 4782
• Main Authors: Zhao, Tan, Tuck-Yun Cheang, Han-Bao, Chong, Ling, Cong, Xiao-Jie, Lu, Chen-Chuang, Li, Xiao-Xiang, Fang, Liu-Bo, Ma, Wang, Gang, An-Wu, Xu
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 01.01.2021
• Subjects: Amino acids; Biomolecules; Carbon nitride; Charge efficiency; Current carriers; Energy conversion; Hydrogen bonds; Hydrogen evolution; Hydrogen production; Hydrogen-based energy; Photocatalysis; Photocatalysts; Triethanolamine; Tryptophan; Water splitting
• ISSN: 2044-4753; 2044-4761
• DOI: 10.1039/d1cy00325a

Photocatalytic water splitting is a promising approach to solar-to-fuel conversion. In recent years, graphitic carbon nitride (g-C3N4) has triggered worldwide interest due to its eco-friendliness, low cost, and visible-light activity as a semiconductor polymer photocatalyst. However, rapid recombination of photoinduced charge carriers and low efficiency are key issues hindering the practical application of g-C3N4 in the efficient photocatalytic hydrogen (H2) production field. Herein, we fabricate a novel g-C3N4-based composite coupled with levorotatory-tryptophan (denoted as CN/l-trp) through π–π interactions and hydrogen bonds to improve the photocatalytic performance. The redox amino acid l-trp small biomolecules act as a hole relay and thus accelerate the transfer process of holes from g-C3N4 to triethanolamine (TEOA), which leads to more electrons shuttled to a Pt cocatalyst, and finally boosts the visible-light photocatalytic H2 evolution reaction (HER). When introducing 10 wt% l-trp, the photocatalytic H2 production rate of g-C3N4/10 wt% l-trp (CN/10 wt% l-trp) loaded with 1.0 wt% Pt cocatalyst composite is prominently enhanced up to 1046.0 μmol h−1 g−1, which is four times that of g-C3N4 loaded with 1.0 wt% Pt cocatalyst (260.2 μmol h−1 g−1). Our study provides a novel strategy to develop an efficient, green and stable g-C3N4-based hybrid photocatalyst for potential application in solar-to-hydrogen energy conversion.