Variation of TiO2/SiO2 mixed layers induced by different Xe+ ion energies

The broadening and optical parameters of TiO2/SiO2 transition layers depending on the ion energy have been investigated using the Rutherford Backscattering Spectrometry (RBS) and Ellipstrometry Spectroscopy (ES) methods. The TiO2/SiO2 samples were irradiated by Xe+ ions with energies of 100, 150, 20...

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Bibliographic Details
Published inarXiv.org
Main Authors Tran Van Phuc, Kulik, Miroslaw, Madadzada, Afag, Kolodynska, Dorota, Le Hong Khiem, Phan Luong Tuan, Nguyen, Ngoc Anh
Format Paper
LanguageEnglish
Published Ithaca Cornell University Library, arXiv.org 03.09.2020
Subjects
Angle of reflection
Backscattering
Implantation
Mathematical analysis
Refractivity
Reinforced reaction injection molding
Silicon dioxide
Thickness
Titanium dioxide
Transition layers
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Summary:The broadening and optical parameters of TiO2/SiO2 transition layers depending on the ion energy have been investigated using the Rutherford Backscattering Spectrometry (RBS) and Ellipstrometry Spectroscopy (ES) methods. The TiO2/SiO2 samples were irradiated by Xe+ ions with energies of 100, 150, 200 and 250 keV. The depth profiles of the elements determined by the RBS spectra show the structure and thickness of the TiO2/SiO2 transition layers before and after implantation. We have found that the thickness of the transition region between the TiO2 and SiO2 layers increases with the increasing incident ion energy. This phenomenon indicates an increasing amount of atomic mixing at the TiO2/SiO2 interface. In addition, the variation of transition layers could be explained by defect depth profiles and ions energy transferred in the mixed layers by means of SRIM calculations. The thickness obtained from the RBS is in good agreement with that measured using the ES method. Based on these obtained results, we have also investigated the optical constants of implanted and non-implanted TiO2/SiO2 structures. The wave forms measured with varying incident angles suggest that the measurements were made close to near the main principle point. The yields of \psi and \delta bands vary at different incident angles, is associated with interference processes of the light reflected from the structures examined. The refractive index and the extinction coefficient were found to increase after implantation taking place up to 200-keV Xe and then decrease at 250 keV.
ISSN:2331-8422