Palladium and platinum complexes of (L)-PhePHos: Acetyl-p-(diphenylphosphino)-(L)-phenylalanine methyl ester - a chiral ligand for transition metal complexation
The crystal structure of the new phenylalanine-based phosphino amino acid L-PhePhos and its reactivity to form the Pd and Pt complexes (L-PhePhos)PdCl2 and (L-PhePhos)PtCl2 is reported. A new platinum hydride was quantitatively formed in the reaction of (L-PhePhos)PtCl2 with NaBH4.
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Published in | Canadian journal of chemistry Vol. 80; no. 11; p. 1562 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Ottawa
Canadian Science Publishing NRC Research Press
01.11.2002
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Subjects | |
Online Access | Get full text |
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Summary: | The crystal structure of the new phenylalanine-based phosphino amino acid L-PhePhos and its reactivity to form the Pd and Pt complexes (L-PhePhos)PdCl2 and (L-PhePhos)PtCl2 is reported. A new platinum hydride was quantitatively formed in the reaction of (L-PhePhos)PtCl2 with NaBH4. |
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ISSN: | 0008-4042 1480-3291 |