Palladium and platinum complexes of (L)-PhePHos: Acetyl-p-(diphenylphosphino)-(L)-phenylalanine methyl ester - a chiral ligand for transition metal complexation

The crystal structure of the new phenylalanine-based phosphino amino acid L-PhePhos and its reactivity to form the Pd and Pt complexes (L-PhePhos)PdCl2 and (L-PhePhos)PtCl2 is reported. A new platinum hydride was quantitatively formed in the reaction of (L-PhePhos)PtCl2 with NaBH4.

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Bibliographic Details
Published inCanadian journal of chemistry Vol. 80; no. 11; p. 1562
Main Authors Iyengar, Vineeth, Galka, Patrycja V, Pletsch, Andreas, Heinz-Bernhard Kraatz
Format Journal Article
LanguageEnglish
Published Ottawa Canadian Science Publishing NRC Research Press 01.11.2002
Subjects
Amino acids
Chemical bonds
Chemistry
Metals
Organometallic compounds
Palladium
Palladium compounds
Phosphorus compounds
Platinum
Platinum compounds
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Summary:The crystal structure of the new phenylalanine-based phosphino amino acid L-PhePhos and its reactivity to form the Pd and Pt complexes (L-PhePhos)PdCl2 and (L-PhePhos)PtCl2 is reported. A new platinum hydride was quantitatively formed in the reaction of (L-PhePhos)PtCl2 with NaBH4.
ISSN:0008-4042
1480-3291