NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N'N' (CH^sub 2^CO^sub 2^)(CH^sub 2^CO^sub 2^H)^sub 3^ ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY

Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating...

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Published inJournal of engineering studies and research Vol. 23; no. 4; pp. 32 - 36
Main Authors Seck, Gorgui Awa, Sene, Aboubacry, Diop, Libasse
Format Journal Article
LanguageEnglish
Published Bacau Universitatea "Vasile Alecsandri" din Bacau 01.10.2017
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Abstract Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH-O, OH-Cl or NH-Cl or O hydrogen bonds may lead to supramolecular architectures.
AbstractList Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH-O, OH-Cl or NH-Cl or O hydrogen bonds may lead to supramolecular architectures.
Author Sene, Aboubacry
Diop, Libasse
Seck, Gorgui Awa
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Snippet Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and...
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StartPage 32
SubjectTerms Adducts
Anions
Antimony
Derivatives
Halides
Hydrogen bonds
Ligands
Tin
Title NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N'N' (CH^sub 2^CO^sub 2^)(CH^sub 2^CO^sub 2^H)^sub 3^ ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
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