NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N'N' (CH^sub 2^CO^sub 2^)(CH^sub 2^CO^sub 2^H)^sub 3^ ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating...
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Published in | Journal of engineering studies and research Vol. 23; no. 4; pp. 32 - 36 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Bacau
Universitatea "Vasile Alecsandri" din Bacau
01.10.2017
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Subjects | |
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Abstract | Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH-O, OH-Cl or NH-Cl or O hydrogen bonds may lead to supramolecular architectures. |
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AbstractList | Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH-O, OH-Cl or NH-Cl or O hydrogen bonds may lead to supramolecular architectures. |
Author | Sene, Aboubacry Diop, Libasse Seck, Gorgui Awa |
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Snippet | Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and... |
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SubjectTerms | Adducts Anions Antimony Derivatives Halides Hydrogen bonds Ligands Tin |
Title | NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N'N' (CH^sub 2^CO^sub 2^)(CH^sub 2^CO^sub 2^H)^sub 3^ ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY |
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