NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N'N' (CH^sub 2^CO^sub 2^)(CH^sub 2^CO^sub 2^H)^sub 3^ ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY

Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating...

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Bibliographic Details
Published inJournal of engineering studies and research Vol. 23; no. 4; pp. 32 - 36
Main Authors Seck, Gorgui Awa, Sene, Aboubacry, Diop, Libasse
Format Journal Article
LanguageEnglish
Published Bacau Universitatea "Vasile Alecsandri" din Bacau 01.10.2017
Subjects
Adducts
Anions
Antimony
Derivatives
Halides
Hydrogen bonds
Ligands
Tin
France
Germany
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Summary:Five Cyclohexyldiamino-NN, N'N'(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH-O, OH-Cl or NH-Cl or O hydrogen bonds may lead to supramolecular architectures.
ISSN:2068-7559
2344-4932