Crystallization Inhibitors: Explaining Experimental Data through Mathematical Models

In this paper we propose a new mathematical model describing the effect of phosphocitrate (PC) on sodium sulphate crystallization inside bricks. This model describes salt and water transport, and crystal formation in a one dimensional symmetry. This is the first study that takes into account mathema...

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Bibliographic Details
Published inarXiv.org
Main Authors Bracciale, M P, Bretti, G, Broggi, A, Ceseri, M, Marrocchi, A, Natalini, R, Russo, C
Format Paper
LanguageEnglish
Published Ithaca Cornell University Library, arXiv.org 21.01.2015
Subjects
Crystallization
Inhibitors
Mathematical models
Nucleation
Parameters
Sodium sulfate
Specific volume
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Summary:In this paper we propose a new mathematical model describing the effect of phosphocitrate (PC) on sodium sulphate crystallization inside bricks. This model describes salt and water transport, and crystal formation in a one dimensional symmetry. This is the first study that takes into account mathematically the effects of inhibitors inside a porous stone. To this aim, we introduce two model parameters: the crystallization rate, which depends on the nucleation rate, and the specific volume of precipitated salt. These two parameters are determined by numerical calibration of our system model for both the treated and non treated case.
ISSN:2331-8422