catena-Poly[[aqua­barium(II)]-[mu]-aqua-bis­([mu]-2'-carboxy­biphenyl-2-carboxyl­ato)]

In the title compound, [Ba{HOOC(C6H4)2CO2}2(H2O)2] or [Ba(C14H9O4)2(H2O)2], the Ba atoms are coordinated by nine O atoms, six from two 2'-carboxybiphenyl-2-carboxylate (Hbpdc-) ligands and three from three coordinated water molecules, resulting in the formation of face-sharing distorted monocap...

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Bibliographic Details
Published inActa crystallographica. Section C, Crystal structure communications Vol. 63; no. 3; p. m91
Main Authors Djehni, Samia, Balegroune, Fadila, Achoura Guehria-Laidoudi, Dahaoui, Slimane, Lecomte, Claude
Format Journal Article
LanguageEnglish
Published Chester Wiley Subscription Services, Inc 01.03.2007
Subjects
Crystal structure
Hydrogen bonds
Polymers
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Summary:In the title compound, [Ba{HOOC(C6H4)2CO2}2(H2O)2] or [Ba(C14H9O4)2(H2O)2], the Ba atoms are coordinated by nine O atoms, six from two 2'-carboxybiphenyl-2-carboxylate (Hbpdc-) ligands and three from three coordinated water molecules, resulting in the formation of face-sharing distorted monocapped square antiprisms. The Hbpdc- ligands bridge the Ba atoms to form a one-dimensional helical polymer, with a Ba...Ba distance across the chain of 4.1386 (17) Angstrom. Adjacent chains are parallel to each other. The two independent ligands are tetradentate and have the same coordination mode, exhibiting micro-oxo bridges and eta8-chelation. The crystal structure is further stabilized by hydrogen bonds within each chain. [PUBLICATION ABSTRACT]
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270107001874