1[lambda]4,4[lambda]4,8[lambda]4,11[lambda]4-Tetra-thia-cyclo-tetra-decane-1,4,7,10-tetra-ylidenetetra-aminium tetra-kis-(2,4,6-trimethylbenzene-sulfonate)
Investigations of the reactivity of the thio-crown [14]aneS4 (1,4,8,11-tetra-thia-cyclo-tetra-decane) towards the aminating agent o -mesitylsulfonyl-hydroxylamine have lead to the crystallization of 1[lambda]4,4[lambda]4,8[lambda]4,11[lambda]4-tetra-thia-cyclo-tetra-decane-1,4,7,10-tetra-ylidenetetr...
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Published in | Acta crystallographica. Section C, Crystal structure communications Vol. 61; no. 6; p. o411 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Chester
Wiley Subscription Services, Inc
01.06.2005
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Subjects | |
Online Access | Get full text |
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Summary: | Investigations of the reactivity of the thio-crown [14]aneS4 (1,4,8,11-tetra-thia-cyclo-tetra-decane) towards the aminating agent o -mesitylsulfonyl-hydroxylamine have lead to the crystallization of 1[lambda]4,4[lambda]4,8[lambda]4,11[lambda]4-tetra-thia-cyclo-tetra-decane-1,4,7,10-tetra-ylidenetetra-aminium tetra-kis-(2,4,6-trimethyl-benzene-sulfonate), C10H28N4S44+(symbol)4C9H11O3S-. The compound crystallizes in a centrosymmetric space group, with half a formula unit in the asymmetric unit. All S atoms within the cationic component are aminated, with the four NH2 substituents arranged in pairs on neighbouring S atoms on opposite faces of the crown. The macrocyclic cation in the compound forms hydrogen bonds with the 2,4,6-trimethyl-benzene-sulfonate anions to create chains, which are further linked into thick two-dimensional sheets.[PUBLICATION ABSTRACT] |
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ISSN: | 0108-2701 1600-5759 |
DOI: | 10.1107/S010827010501437X |