Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (-)-SpiroxinC

Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (-)-spiroxinC.

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Bibliographic Details
Published inAngewandte Chemie Vol. 129; no. 38; p. 11618
Main Authors Ando, Yoshio, Hanaki, Atsuko, Sasaki, Ryota, Ohmori, Ken, Suzuki, Keisuke
Format Journal Article
LanguageGerman
Published Weinheim Wiley Subscription Services, Inc 11.09.2017
Subjects
Chemistry
Enantiomers
Stereospecificity
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Summary:Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (-)-spiroxinC.
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.201705562