Two-temperature synthesis of non-linear optical compound CdGeAs^sub 2

• Published in: Journal of crystal growth Vol. 455; p. 129
• Main Authors: Zhu, Chongqiang, Verozubova, GA, Mironov, Yuri P, Lei, Zuotao, Song, Liangcheng, Ma, Tianhui, Okunev, AO, Yang, Chunhui
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier BV 01.12.2016
• Subjects: Arsenic compounds; Arsenides; Cadmium; Cadmium compounds; Chalcopyrite; Chemical reactions; Chemical synthesis; Crystal structure; Germanium; Intermetallic compounds
• ISSN: 0022-0248; 1873-5002

In this work, we report on a new approach to synthesize large-scale nonlinear optical chalcopyrite compound CdGeAs2 (cadmium germanium arsenide), in which the arsenic (As) precursor and the mixture of the cadmium (Cd) and the germanium (Ge) were separated in two distinct temperature-defined zones of a furnace. Through probing the intermediate product prepared at pre-set temperature points of hot-zone area, it was revealed that the ternary compound CdGeAs2 was formed through chemical reactions among Cd3As2, CdAs2, GeAs, GeAs2 and Ge. A new intermediate crystalline compound, with determined crystal parameter c=0.9139 nm and unknown a parameter, was identified when the temperature of the mixture of Cd and Ge was set to 680 °C, which, however, disappeared when the temperature was set to 770 °C, yielding pure CdGeAs2 product. Most likely, the identified new intermediate compound has layered graphite-like structure. Moreover, we show that the described two-temperature synthesis method allows us to produce near 250 g CdGeAs2 product during one run in a horizontal furnace and 500 g in a tilted horizontal furnace with rotated reactor.