Electrochemical and wear behavior of niobium-vanadium carbide coatings produced on AISI H13 tool steel through thermo-reactive deposition/diffusion/Comportamiento electroquímico y al desgaste de recubrimientos de carburo de niobio-vanadio producidos sobre acero para herramientas AISI H13 por medio de la deposición/difusión termorreactiva

• Published in: Ingeniare : Revista Chilena de Ingenieria Vol. 24; no. 2; p. 206
• Main Authors: Nieto, Fabio Enrique Castillejo, Floréz, Jhon Jairo Olaya, Orjuela, José Edgar Alfonso
• Format: Journal Article
• Language: English
• Published: Arica Universidad de Tarapacá 01.04.2016
• Subjects: Diffusion; Spectrum analysis
• ISSN: 0718-3291; 0718-3305

We deposited of niobium-vanadium carbide coatings on tool steel AISI H13 using the thermo-reactive substrates deposition/diffusion (TRD) technique. The carbides were obtained using salt baths composed of molten borax, ferroniobium, vanadium and aluminum, by heating this mixture at 1020° C for 4 hours. The coatings were characterized morphologically via electron microscopy scanning (SEM), the chemical surface composition was determined through X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDX); the crystal structure was analyzed using x-ray diffraction (XRD), the mechanical properties of the coatings were evaluated using nano-indentation, The tribological properties of the coatings obtained were determined using a Pin-on-disk tribometer and the electrochemical behavior was studied through potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS). The results showed that the hardness of the coated steel increased four times with respect to uncoated steel, and the electrochemical test established that the corrosion current is lower by one order of magnitude for coated steel.