ChemInform Abstract: A Visible Light Photocatalytic Cross-Dehydrogenative Coupling/Dehydrogenation/6[pi]-Cyclization/Oxidation Cascade: Synthesis of 12-Nitroindoloisoquinolines from 2-Aryltetrahydroisoquinolines

A photolytic aerobic oxidative cyclization of 1-nitromethyl substituted tetrahydroisoquinolines (I) and related pyridines (III) in the presence of 1-aminoanthraquinone as the catalyst is developed to yield condensed nitropyrrole derivatives.

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Bibliographic Details
Published inChemInform Vol. 46; no. 41
Main Authors Rusch, Fabian, Unkel, Lisa-Natascha, Alpers, Dirk, Hoffmann, Frank, Brasholz, Malte
Format Journal Article
LanguageEnglish
Published Frankfurt Wiley Subscription Services, Inc 01.10.2015
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Summary:A photolytic aerobic oxidative cyclization of 1-nitromethyl substituted tetrahydroisoquinolines (I) and related pyridines (III) in the presence of 1-aminoanthraquinone as the catalyst is developed to yield condensed nitropyrrole derivatives.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201541193