An effective method to reduce residual lithium compounds on Ni-rich Li[Ni^sub 0.6^Co^sub 0.2^Mn^sub 0.2^]O2 active material using a phosphoric acid derived Li^sub 3^PO^sub 4^ nanolayer

• Published in: Nano research Vol. 8; no. 5; p. 1464
• Main Authors: Jo, Chang-heum, Cho, Dae-hyun, Noh, Hyung-joo, Yashiro, Hithshi, Sun, Yang-kook, Myung, Seung Taek
• Format: Journal Article
• Language: English
• Published: Beijing Springer Nature B.V 01.05.2015
• Subjects: Aqueous solutions; Atoms & subatomic particles; Electrodes; Electrolytes; Fluorides; Lithium; Protective coatings; Retention; Temperature; X-ray diffraction; South Korea
• ISSN: 1998-0124; 1998-0000
• DOI: 10.1007/s12274-014-0631-8

The Ni-rich Li[Ni^sub 0.6^Co^sub 0.2^Mn^sub 0.2^]O2 surface has been modified with H^sub 3^PO^sub 4^. After coating at 80 °C, the products were heated further at a moderate temperature of 500 °C in air, when the added H^sub 3^PO^sub 4^ transformed to Li^sub 3^PO^sub 4^ after reacting with residual LiOH and Li^sub 2^CO3 on the surface. A thin and uniform smooth nanolayer (< 10 nm) was observed on the surface of Li[Ni^sub 0.6^Co^sub 0.2^Mn^sub 0.2^]O2 as confirmed by transmission electron microscopy (TEM). Time-of-flight secondary ion mass spectroscopic (ToF-SIMS) data exhibit the presence of LiP^sup +^, LiPO^sup +^, and Li^sub 2^PO^sub 2^^sup +^ fragments, indicating the formation of the Li^sub 3^PO^sub 4^ coating layer on the surface of the Li[Ni^sub 0.6^Co^sub 0.2^Mn^sub 0.2^]O2. As a result, the amounts of residual lithium compounds, such as LiOH and Li^sub 2^CO3, are significantly reduced. As a consequence, the Li^sub 3^PO^sub 4^-coated Li[Ni^sub 0.6^Co^sub 0.2^Mn^sub 0.2^]O2 exhibits noticeable improvement in capacity retention and rate capability due to the reduction of residual LiOH and Li^sub 2^CO3. Further investigation of the extensively cycled electrodes by X-ray diffraction (XRD), TEM, and ToF-SIMS demonstrated that the Li^sub 3^PO^sub 4^ coating layers have multi-functions: Absorption of water in the electrolyte that lowers the HF level, HF scavenging, and protection of the active materials from deleterious side reactions with the electrolyte during extensive cycling, enabling high capacity retention over 1,000 cycles. [Figure not available: see fulltext.]