Cover Picture: Double CaromH Activation Associated with Etheral Oxygen Insertion to Phenazine Architecture in Oxidisable Ruthenium(III) Complexes: A Mechanistic Insight (Chem. Eur. J. 10/2014)

Three examples of unusual double aromatic CH bond activation associated with insertion of etheral oxygen atom to phenazine architecture in Ru(III) complexes are reported. The chemical transformations have led to the formation of new Ru(IV) complexes with angular pentacyclo heterocyclic ligands. A me...

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Published inChemistry : a European journal Vol. 20; no. 10; p. 2677
Main Authors Roy, Suman K, Samanta, Subhas, Chowdhury, Nabanita Saha, Mondal, Tapan K, Goswami, Sreebrata
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 03.03.2014
Subjects
Chemistry
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Summary:Three examples of unusual double aromatic CH bond activation associated with insertion of etheral oxygen atom to phenazine architecture in Ru(III) complexes are reported. The chemical transformations have led to the formation of new Ru(IV) complexes with angular pentacyclo heterocyclic ligands. A mechanistic investigation indicates that the overall process is a combination of successive steps involving air (O2 ) and H2 O.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201490037