TiO^sub 2-x^ nanoparticles synthesized using He/Ar thermal plasma and their effectiveness on low-concentration mercury vapor removal

• Published in: Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology Vol. 13; no. 10; p. 4739
• Main Authors: Tsai, Cheng-yen, Hsi, Hsing-cheng, Bai, Hsunling, Fan, Kuo-shuh, Chen, Chienchih
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Nature B.V 01.10.2011
• Subjects: Irradiation; Mercury; Nanoparticles; Titanium dioxide; Tungsten
• ISSN: 1388-0764; 1572-896X
• DOI: 10.1007/s11051-011-0442-8

Oxygen-vacant titanium dioxide (TiO^sub 2-x^) nanoparticles were synthesized using thermal plasma as a heating source at various applied plasma currents and He/Ar ratios. Samples with diverse characteristics were developed and the mercury removal effectiveness was subsequently evaluated. TiO2 nanoparticles possessing high purity and uniform particle sizes were successfully synthesized using metal titanium and O2 as precursors and Ar as plasma gas. TiO^sub 2-x^ in anatase phase with a particle size at 5-10 nm was formed at the He/Ar volume ratio of 25/75. Further increasing the He/Ar ratio elevated the plasma temperature, causing the tungsten to melt, vaporize from the cathode, and then dope into the formed TiO2 nanoparticles. The doped W appeared to inhibit the growth of nanoparticles and decrease the crystallinity of formed anatase. The effectiveness of oxygen-vacant sites on Hg^sup 0^ removal under the visible light circumstance was confirmed. Hg^sup 0^ removal by the TiO^sub 2-x^ nanoparticles was enhanced by increasing the O2 concentration. However, moisture reduced Hg^sup 0^ capture, especially when light irradiation was applied. The reduction in Hg^sup 0^ capture may be resulted from the competitive adsorption of H2O on the active sites of TiO^sub 2-x^ with Hg^sup 0^ and transformed Hg^sup 2+^.[PUBLICATION ABSTRACT]