Preparation and structural-bonding characterization of a 50-electron trianglular cobalt cluster, [Co(C5H4CO2Me)]3(S)(NtBu), with triply bridging sulfido and imido ligands: singlet-triplet equilibrium in solid and solution states
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| Published in | Inorganic chemistry Vol. 27; no. 17; pp. 2958 - 2963 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Washington, DC
American Chemical Society
1988
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| Subjects | |
| Online Access | Get full text |
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| Author | GUOBAO CHENG OKADA, T WAKATSUKI, Y YAMAZAKI, H |
|---|---|
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| Keywords | Cobalt Complexes Thio complex Chemical solution Temperature Trinuclear complex Orbital interaction Theoretical study Transition metal Complexes Experimental study Inorganic compound Magnetic susceptibility Mu complex Least squares method Preparation Extended Hueckel method NMR spectrum Conformation Crystalline structure |
| Language | English |
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| SubjectTerms | Atomic and molecular physics Exact sciences and technology Interatomic distances and angles Molecular properties and interactions with photons Physics Properties of molecules and molecular ions |
| Title | Preparation and structural-bonding characterization of a 50-electron trianglular cobalt cluster, [Co(C5H4CO2Me)]3(S)(NtBu), with triply bridging sulfido and imido ligands: singlet-triplet equilibrium in solid and solution states |
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